My husband is having the same issue with his copy of CS6 on a Mac with OS X 10.8.2 and CS6 13.0.3 x64. Have they resolved this issue yet beyond the help file that says to keep your serial number in a text doc so you can keep pasting it over and over again? In his case, it probably wouldn't be so bad if it just happened when turning on the computer or starting up the program, but his will actually shut down the program while he's in the middle of editing a photo to ask for the serial number again, so he loses all of his work.
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